Browsing by Author "Vicente, Enoque Mendes."
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Item Aspects of the engineering geology of Maputo City, Mozambique.(2011) Vicente, Enoque Mendes.; Schreiner, Hilson Deneys.; Jermy, Colin A.; Richards, Nicholas.The geological formations of Maputo City, which are mainly unconsolidated materials with soil like properties, are described in terms of their engineering geological and geotechnical characteristics with relevance to their distribution patterns and spatial trends. Problematic conditions such as collapse potential characteristics, loose aeolian sand dune deposits and loose sand plains characterize many of the materials. The geological characteristics combined with anthropogenic interference such as intensive urbanization with inappropriate land use, construction in sensitive areas like steep sandy slopes has led to many problems including slope stability. Foundation problems with building settlement and gully erosion also occur. The aim of this research was to study the engineering geological characteristics and the geotechnical properties of the geological formations of Maputo City and various related problems. Special relevance has been given to the understanding of three specific problems: building damage, gully erosion and slope instability. The geological formations are predominantly sandy (coarse to very fine sand) with very low clay content, are non-plastic and are classified as from the group SP-SM which are poorlygraded sand with silt. The majority of the materials are loose and normally consolidated with a high level of residual strength. Assessment of collapse settlement through double consolidation technique indicated soil compressibility and significant sensibility to collapse upon wetting. Truly collapsible soils that show full collapse of the soil structure were identified in 33% of the tested materials where the highest collapse behaviour reached values above 5%, predicted to cause moderate trouble in foundation design. Some of the bonded materials are bonded (evident in 67% of samples tested). Bonding was confirmed by comparing the compressibility of the undisturbed and remoulded samples. The remoulded samples showed a significantly higher compression than that of the bonded materials as part of the stress applied is carried by the bonds themselves, as the bonded material is stiffer than the same without bonds. The curves of the remoulded samples were used to establish the limit between the stable and meta-stable states of the material. A qualitative evaluation of the erosion susceptibility was investigated by physical tests such as the crumb test, shear strength and chemical indicators while a quantitative evaluation of the erodibility characteristics was obtained using a flume test. Some correlations were found between the results of various methods. Almost all samples that were found to be dispersive with ESP were also dispersive with TDS vs. %Na and SAR. Results of the flume erodibility test have very little correlation with the chemical properties related to dispersion revealing that the erosion susceptibility and gullying in Maputo City have more relation to the physical processes than to the dispersion related chemical properties of the soils. The positive identification of dispersive and erodible soils can only be carried out using a combination of various techniques. Therefore, a new rating system for erosion susceptibility of sandy soils combining the physical and chemical factors of dispersion is proposed including the flume test, crumb test, TDS/%Na, SAR and ESP. The proposed rating system was applied to the tested soils of Maputo City. Fifteen samples (83% of the rated samples) were classified with intermediate susceptibility to erosion while 3 samples (17%) were classified as having a low susceptibility to erosion. The highest rating scores were obtained by the same samples that showed dispersive behaviour with SAR, ESP and TDS/%Na. This group of samples was of intermediate erodibility in the flume test. The slope instability mechanisms observed in Maputo City are predominantly rotational failures with a mass of soil sliding along a curved surface of rupture followed by sand flow at the toe as failure occurs in the presence of excess water. Four groups of factors account for the slope instability problems in Maputo City: geomorphological causes, physical and meteorological causes, geological and geotechnical properties of soils, and anthropogenic causes. The mechanism of failure is mostly due to the loss of matric suction of soils in the presence of rainwater and possibly from destruction of bonding agents. Factors of safety values indicate that the slopes are generally unstable with the control being the slope angle. The slopes in the Polana-Caniço and Ferroviário Quarters show high factor of safety values but is the area most affected by slope instability. Slope failure in these areas is intrinsically caused by anthropogenic factors related to inappropriate land use planning. The gully sidewalls are unstable as the slope created is very steep. The slope at Friedrich Engels Avenue causes most concern due not only to the slope height and angle but also to the size and number of buildings constructed at the crest, mainly high rise buildings along the Julius Nyerere Avenue, the integrity of which could be threatened by a landslide event (this slope has recently been affected by active landslides).Item Impact of alluvial gold mining on surface water quality in the Revue basin-Manica District, Mozambique.(2000) Vicente, Enoque Mendes.; Marsh, Carol A.The upper part of the Revue basin in the Manica District, Mozambique is located in a mountainous area underlain by rocks of the Manica greenstone belt. This greenstone belt has alluvial gold deposits in the Revue river and its tributaries Chua and Zambuzi. Alluvial gold in the Manica District has been mined by local people using artisanal mining methods (panning) and by small scale companies. The recovery process of gold involves washing of the auriferous gravel with large quantities of water and the surface water quality has been impaired in this process. The aim of this dissertation is to assess the impact of alluvial gold mining on surface water quality in the Revue basin. Physical and chemical characteristics of the surface water were determined upstream of, within and downstream of the mining area and in the main tributaries immediately before flowing into the Revue river. Upstream of the mining area the water is clear and the rock types of the Manica greenstone belt are likely to be the only source of metals dissolved in the water. Metal concentrations are generally low except Cd, Mo and Ni but the water in this area meets all World Health Organization (WHO) recommendations for drinking water. In contrast within the mining area there are signs of pollution. The water is cloudy and the highest concentrations of most metals are found in the lower part of this area where mining activity is very intense. Thus, the alluvial gold mining is responsible for elevated metal concentrations and constitutes the major point source of pollution in the Revue basin. Water quality within the mining area has been affected and metals Ba, Pb and Mn have concentrations exceeding the WHO recommended values for drinking water. Downstream of the mining area the impounded water in the Chicamba Dam, which is the source of potable water for Chimoio City, reduces the water flow in the Revue river and sedimentation of suspended sediments occurs, together with associated adsorption and precipitation processes. This result in general improvement of water quality with only Ba and Pb concentrations remaining above the WHO recommended values for drinking water. Increase in concentration of metals AI, Ba, K, Pb and Sr occurring in the Chicamba Dam is likely to be due to input to the dam of water from rivers which cross the Granite-gneiss Complex. Geochemical speciation modelling using MINTEQA2 program suggests that the behaviour of metals Cr, AI, Mn and Fe is controlled by redox and precipitation reactions while the behaviour of As, Cd, Zn, Cu, Ni, Pb, Ba and Ca is controlled by adsorption on the sediment surfaces. Changes in environmental conditions, such as pH and dissolved organic matter (DOM) could result in metals being released back into the water. Modelling the effect of a change in pH and variation in DOM indicate that adsorption and precipitation would decrease with decreasing pH values and with increasing DOM. The chemical form of dissolved metals, the type of interactive processes (absorption and precipitation) and concentration of particulate matter gives the distribution of pollutants while the transport process affect the fate of pollutants in the Revue river water.